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15) Favorite Villain
It's a tough call. But I think it's a tie between Rezo and Zuuma
Rezo would be a shoe-in if it weren't for Evolution-R. Before that season; there was a lot of mystery surrounding him. The end of the first season let the viewer decide if Rezo himself was evil or if he was just corrupted by Shabranigdo until he lost his mind and identity. I REALLY wish that Evo-R hadn't brought him back and confirmed that he was an asshole all along. It made him a LOT less interesting.
Zuuma is cool because he managed to be a formidable opponent for Lina despite the fact that, for most of the novel/anime, he was just a normal human with mad ninja skillz. And his motive for wanting Lina dead was understandable (even if the incident that pissed him off wasn't really Lina's fault). I was really happy to see him make an appearance in the last season of the anime!
16) Least Favorite Villain
Again, I'm gonna bash the TRY aliens. On paper, their motives were complex and deep and all that. But as characters they just fell flat and they were no fun to watch.
On the flipside, Valgaav's motivation was pretty stupid and generic (I had a crappy childhood and my BFF died. Therefore I want to die and take the whole world down with me!!). But he didn't bug me as much because at least he was fun to watch and came across as somewhat interesting. Go fig. :P